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Mass Spectrometry
NIR Spectroscopy

 
European Journal of Mass Spectrometry (EJMS)

Volume 10 Issue 6 (2004)

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Special Issue: Dedicated to John L. Holmes


Pages 0–0
doi: 10.1255/ejms.713
Book Review: ToF-SIMS: Surface Analysis by Mass Spectrometry
Scott D. Hanton
Air Products and Chemicals, Inc., 7201 Hamilton Blvd, Allentown, PA 18195, USA. E-mail: hantonsd@apci.com

Pages 0–0
doi: 10.1255/ejms.724
Obituary: John Robert Chapman 1939–2004
Peter J. Derrick

Pages 0–0
doi: 10.1255/ejms.725
Special issue of the European Journal of Mass Spectrometry on gas- phase ion chemistry and thermochemistry dedicated to John L. Holmes
Paul M. Mayer
Chemistry Department, University of Ottawa, Ottawa, Canada K1N 6N5
Leo Radom
School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia

Pages 747–754
doi: 10.1255/ejms.683
A study of the methane catalyzed isomerization of HCO+ to HOC+ and the elimination of methane from metastable methoxymethyl cation
Travis D. Fridgen*
Department of Chemistry, Wilfrid Laurier University, Waterloo, Ontario, Canada, N2L 3C5
John L. Holmes
Department of Chemistry, University of Ottawa, Ottawa, Ontario, Canada, K1N 6N5

Pages 755–758
doi: 10.1255/ejms.697
Isolation of isomers based on hydrogen/deuterium exchange in the gas phase
Ulf Mazurek,a,* Melinda A. McFarland,b Alan G. Marshall,b,c Chava Lifshitza*
aDepartment of Physical Chemistry and The Farkas Center for Light Induced Processes, The Hebrew University of Jerusalem, Giv’at Ram, Jerusalem 91904, Israel. E-mail: ykv@chem.ch.huji.ac.il
bDepartment of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA
cIon Cyclotron Resonance Program, National High Magnetic Field Laboratory, Florida State University, 1800 East Paul Dirac Drive, Tallahassee, FL 32310-4005, USA

Pages 759–766
doi: 10.1255/ejms.681
Heat of formation for the methylenimmonium cation by photoionization mass spectrometry
Zoë A. Harvey and John C. Traeger*
Department of Chemistry, La Trobe University, Victoria 3086, Australia. E-mail: j.traeger@latrobe.edu.au

Pages 767–774
doi: 10.1255/ejms.708
CH4 Loss from (CH)4N+ revisited: how does this high energy elimination compete with ·CH3 loss?
Charles E. Hudson,a Lawrence L. Griffinb and David J. McAdooa,*
aDepartment of Neuroscience and Cell Biology, University of Texas Medical Branch, 301 University Boulevard, Galveston, TX 77555–1043, USA. E-mail: djmcadoo@utmb.edu
bDepartment of Marine Sciences, Texas A&M University at Galveston, Galveston, TX 77553, USA

Pages 775–782
doi: 10.1255/ejms.707
The formation and heats of formation of simple α-distonic ions
Lars Bo Jensen and Steen Hammerum
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark

Pages 783–790
doi: 10.1255/ejms.706
The unimolecular reactions of ionized methylacetamides
Lars Bo Jensen and Steen Hammerum
Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark

Pages 791–800
doi: 10.1255/ejms.690
Energy and stability of protonated ketenes: inductive and resonance effects
Henri K. Ervasti,a Peter C. Burgersb and Paul J.A. Ruttinka,*
aTheoretical Chemistry Group, Department of Chemistry, University of Utrecht, 3584 CH Utrecht, The Netherlands. E-mail: p.j.a.ruttink@chem.uu.nl
bLaboratory for Neuro-Oncology, Department of Neurology, Erasmus MC, PO Box 1738, 3000 DR Rotterdam, The Netherlands

Pages 801–812
doi: 10.1255/ejms.696
The decarbonylation of the acetamide radical cation and the enolization of its dimer by self-catalysis
Moschoula A. Trikoupis,a Paul J.A. Ruttink,b Peter C. Burgersc and Johan K. Terlouwd,*
aLaboratory Services Branch, Ministry of the Environment, Etobicoke, Ontario M9P 3V6, Canada
bTheoretical Chemistry Group, Department of Chemistry, University of Utrecht, 3584 CH Utrecht, The Netherlands
cLaboratory for Neuro-Oncology, Department of Neurology, Erasmus MC, PO Box 1738, 3000 DR Rotterdam, The Netherlands
dDepartment of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada. E-mail: terlouwj@univmail.cis.mcmaster.ca

Pages 813–818
doi: 10.1255/ejms.699
Tetrafluorobenzyne thermochemistry: experiment and theory
Lawrence M. Pratt*
Department of Chemistry, Fisk University, Nashville, TN 37208, USA
Alireza Fattahi and Steven R. Kass*
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA. E-mail: kass@chem.umn.edu

Pages 819–828
doi: 10.1255/ejms.685
The C3H7+ appearance energy from 2- iodopropane and 2-chloropropane studied by threshold photoelectron photoion coincidence
Adam Brooks,a Kai-Chung Lau,b C.Y. Ng,b and Tomas Baera
aDepartment of Chemistry University of North Carolina, Chapel Hill, NC 27599-3290, USA
bDepartment of Chemistry, University of California, Davis, CA 95616, USA

Pages 829–836
doi: 10.1255/ejms.682
The gas-phase rearrangement of HCCBCCH to a trans pentacyclic isomer. A joint experimental and theoretical study
Andrew M. McAnoy and John H. Bowie*
Department of Chemistry, The University of Adelaide, South Australia, Australia, 5005. E-mail: john.bowie@adelaide.edu.au

Pages 837–846
doi: 10.1255/ejms.684
Water dimer proton affinity from the kinetic method: dissociation energy of the water dimer
Daniel J. Goebbert, Paul G. Wenthold*
Department of Chemistry, Purdue University, 560 Oval Dr, West Lafayette, IN 47907, USA. E- mail:pgw@purdue.edu

Pages 847–856
doi: 10.1255/ejms.695
Gas-phase halide affinity of aliphatic alcohols estimated by the kinetic method
Rodinei Augusti,a Daniella V. Augusti,a Hao Chen,b and R. Graham Cooksb,*
aDepartamento de Química, Universidade Federal de Minas Gerais, Belo Horizonte/ MG, Brazil 31270-901
bDepartment of Chemistry, Purdue University, West Lafayette, IN 47907, USA

Pages 857–868
doi: 10.1255/ejms.702
Unimolecular fragmentation and isomerization of gaseous arsanyl cations Y- C6H4As+X (X = F, Cl, Br, I) The role of non-classical nido structures
Dirk Kirchhoff and Hans-Friedrich Grützmacher*
Fakultät für Chemie der Universität Bielefeld, Postfach 10 01 31, D-33501 Bielefeld, Germany. E-mail: hans- friedrich.gruetzmacher@uni-bielefeld.de
Hansjörg Grützmacher
Department of Chemistry and Applied Biosciences, HCI H 131 ETH- Hönggerberg, CH-8093 Zürich, Switzerland

Pages 869–880
doi: 10.1255/ejms.680
Electron-rich radicals by neutralization–reionization mass spectrometry. Generation, dissociations and energetics of the hydrogen atom adduct to acetamide
Francis Tam, Erik A. Syrstad, Xiaohong Chen and Frantiček Tureček*
Department of Chemistry, Bagley Hall, Box 351700, University of Washington, Seattle, WA 98195-1700, USA

Pages 881–888
doi: 10.1255/ejms.705
Gas-phase protonation of benzocycloalkenes
Barbara Chiavarino, Maria Elisa Crestoni and Simonetta Fornarini*
Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università di Roma "La Sapienza", P. le A. Moro 5, I-00185 Roma, Italy. E-mail: simonetta.fornarini@uniroma1.it

Pages 889–898
doi: 10.1255/ejms.686
A specific gas phase substitution reaction between enol radical cations and t-butyl nitrite
Pascal Gerbaux,a* Pascale Wantier,a* Pham Can Namb, Minh Tho Nguyenb, Guy Bouchouxc and Robert Flammanga
aOrganic Chemistry Laboratory, University of Mons-Hainaut, 19 Avenue Maistriau, B-7000 Mons, Belgium
bDepartment of Chemistry, University of Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium
cLaboratoire des Mécanismes Réactionnels, UMR CNRS 7651, Ecole Polytechnique, F-91128 Palaiseau Cedex, France

Pages 899–908
doi: 10.1255/ejms.689
Evidence for the participation of excited electronic states in the unimolecular dissociation reactions of ionic complexes between NO and aromatic compounds
Julie A.D. Grabowy and Paul M. Mayer*
Chemistry Department, University of Ottawa, Ottawa, Canada K1N 6N5. E-mail: pmayer@science.uottawa.ca

Pages 909–920
doi: 10.1255/ejms.700
Li+-coordinated polyglycol radicals: ion–molecule reactions with alkenes and ethers
Michael J. Polce, Jody M. Modarellia and Chrys Wesdemiotis
Department of Chemistry, The University of Akron, Akron, Ohio 44325, USA. E-mail: wesdemiotis@uakron.edu

Pages 921–930
doi: 10.1255/ejms.701
Li+ vs Cu+ association to toluene, phenylsilane and phenylgermane. Conventional vs non-conventional π-complexes
Inés Corral, Otilia Mó and Manuel Yáñez
Departamento de Química, C-9, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain

Pages 931–940
doi: 10.1255/ejms.688
Fragmentation of singly charged silver/α,Ω-diaminoalkane complexes: competition between the loss of H2 and AgH molecules
Tujin Shi, Junfang Zhao, Tamer Shoeib, K.W. Michael Siu and Alan C. Hopkinson
Department of Chemistry and Centre for Research in Mass Spectrometry, York University, 4700 Keele Street, Toronto, Ontario, Canada M3J 1P3. E-mail: ach@yorku.ca

Pages 941–948
doi: 10.1255/ejms.698
Ring complexes of S-nitrosothiols with CU+: a density functional theory study
Cristina Baciu, Kyung-Bin Cho and James W. Gauld*
Department of Chemistry and Biochemistry, University of Windsor, Windsor, ON N9B 3P4, Canada

Pages 949–962
doi: 10.1255/ejms.694
Gas-phase kinetic measurements of the ligation of Ni+, Cu+, Ni(pyrrole)1,2+ and Cu(pyrrole)1,2+ with CO2, D2O, NH3 and NO
Michael J. Y. Jarvis, Voislav Blagojevic, Gregory K. Koyanagi and Diethard K. Bohme*
Department of Chemistry, Centre for Research in Mass Spectrometry and Centre for Research in Earth and Space Science, York University, Toronto, Ontario, Canada, M3J 1P3. E-mail: dkbohme@yorku.ca

Pages 963–976
doi: 10.1255/ejms.693
Guided ion beam study of potential energy surfaces for platinum interactions with nitrogen oxides
Xiao-Guang Zhang and P. B. Armentrout*
Department of Chemistry, University of Utah, Salt Lake City, Utah 84112-0850, USA

Pages 977–992
doi: 10.1255/ejms.687
Protonation thermochemistry of α-aminoacids bearing a basic residue
Guy Bouchoux,*a David-Alexandre Buisson,b Cyril Colasa and Michel Sabliera
aLaboratoire des Mécanismes Réactionnels, UMR 7651, Ecole Polytechnique, 91128 Palaiseau cedex, France
bCEN Saclay 91190 Gif sur Yvette cedex, France.

Pages 993–1002
doi: 10.1255/ejms.692
Prediction of the charge states of folded proteins in electrospray ionization
Michael Peschke, Udo H. Verkerk and Paul Kebarle*
Department of Chemistry, University of Alberta, Edmonton Canada T6G 2G2

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