Abstract

European Journal of Mass Spectrometry
Volume 13 Issue 2, Pages 115–123 (2007)
doi: 10.1255/ejms.851

Space charge effect in spectrometers of ion mobility increment with planar drift chamber

A.A. Elistratov and L.A. Sherbakov
The Institute for Cryptosystems, Communication and Informatics, Moscow, Russian Federation. E-mail: SherbakovLA@mail.ru

The effect of space charge on the ion beam in a spectrometer of ion mobility increment with the planar drift chamber has been investigated. A model for the drift of ions under a non-uniform high-frequency electric field^1–3 has been developed recently. We have amplified this model by taking space charge effect into account. The ion peak shape taking into consideration the space charge effect is obtained. The output current saturation effect limiting the rise of the ion peak with increasing ion density at the input of the drift chamber of a spectrometer is observed. We show that the saturation effect is caused by the following phenomenon. The maximum possible output ion density exists, depending on the ion type (constant ion mobility, k₀) and the time of the motion of ions through the drift chamber. At the same time, the ion density does not depend on the parameters of the drift chamber.

Keywords: FAIMS, space charge effect, ion mobility

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