Abstract

European Journal of Mass Spectrometry
Volume 12 Issue 4, Pages 271–277 (2006)
doi: 10.1255/ejms.816

Gas chromatography/mass spectrometric analysis of N,N- dialkylaminoethyl-2-methoxyethyl ethers as the decontamination markers of N,N-dialkylaminoethyl-2-chlorides for verification of the Chemical Weapons Convention

Arvinda K. Gupta, Deepak Pardasani, Pankaj K. Kanaujia, Vijay Tak and Devendra K. Dubey^*
Vertox Laboratory, Defence Research and Development Establishment, Gwalior, India. E-mail: dkdubey@rediffmail.com

The detection and identification of markers of scheduled chemicals plays an important role in verification analysis of Chemical Weapons Convention (CWC). This paper describes the gas chromatography electron ionization mass spectrometric (GC/EI-MS) analysis of N,N-dialkylaminoethyl-2-methoxyethyl ethers (DAEMEs), which are identified as characteristic degradation markers of N,N-dialkylaminoethyl-2-chlorides. N,N-dialkylaminoethyl-2-chlorides produced DAEMEs on reacting with the universally used decontamination solution (DS- 2). DAEMEs were prepared by condensation of N,N-dialkylaminoethyl-2-chlorides with 2-methoxy ethanol the active ingredient of DS-2. Based on the GC/EI-MS analysis of DAEMEs the generalized fragmentation routes are proposed which rationalize most of the characteristic ions in EI-MS.

Keywords: Chemical Weapons Convention, verification, N,N-dialkylaminoethyl-2-methoxyethyl ethers, N,N-dialkylaminoethyl-2-­chlorides, GC/MS, degradation markers, chemical warfare agents, detection

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